Cyclic polyhydroxy ketones. II. xylo-trihydroxycyclohexenediolic acid and keto-inositols
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چکیده
منابع مشابه
One-pot synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane (Ph3PNNC), cyclic ketones and ferrocene carboxylic acid
Reactions of N-isocyaniminotriphenylphosphorane with a cyclic ketone in the presence of ferrocene carboxylic acid proceeded smoothly at room temperature and in neutral conditions to afford ferrocene-containing 1,3,4-oxadiazole derivatives in high yields. The reaction proceeded smoothly and cleanly under mild conditions and no side reactions were observed. The structures of the products were ded...
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ion from the solvent by the excited cyclocamphanone to give (XXV), cleavage of the cyclopropane ring to give (XXXVI), and hydrogen atom transfer and ketonization. This postulated route for the isomerization of cyclocamphanone to (XXXIV) is based on the proposal by Srinivasan for the route of isomerization of camphor to the ketone (XIV)'°. The photolysis of (XXXIV) to give (XVI) finds close anal...
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ژورنال
عنوان ژورنال: Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
سال: 1964
ISSN: 0022-4332
DOI: 10.6028/jres.068a.026